The rates of absorption of chlorine diluted with nitrogen into aqueous acidic solutions of ferrous chloride of various concentrations were measured at l&25,35 and 45°C using a batlled agitated vessel operated batchwise. The experimental results were analysed with the chemical absorption theory based
Oxidation of chloride to chlorine in aqueous solution via redox catalysis
✍ Scribed by J. Kiwi; M. Grätzel
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 668 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
This study reports evidence for the generation of chlorine from NaCl as starting material when aqueous-solution oxidizing materials such as Ce(SO& -4Hz0, Suprov (perisophthalic acid), MPPA (monoperouyphthalic acid) and NaBOs. 4H20 are brought in contact with catalytic amounts of powdered Ru02. Cl2 evolution takes place, showing that very low energy losses occur when a suitable redox catalyst mediates the oxidation step.
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