Zirconium-mediated asymmetric Baeyer-Vil
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Carsten Bolm; Oliver Beckmann
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Article
📅
2000
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John Wiley and Sons
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English
⚖ 87 KB
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Combinations of axially chiral C2-symmetric diols were used as ligands in zirconium-mediated Baeyer-Villiger reactions. The in situ preformed Zr-diol species proved effective in the asymmetric oxidation of bicyclic and monosubstituted cyclobutanones when a hydroperoxide was employed as oxidant. Asym