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Oxidation of ascorbic acid by nitrous acid: conditions where autoxidation of nitric oxide is rate determining

โœ Scribed by Beake, Ben D.; Moodie, Roy B.; Smith, Davina

Book ID
121232669
Publisher
Royal Society of Chemistry
Year
1995
Tongue
English
Weight
277 KB
Volume
7
Category
Article
ISSN
1472-779X

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๐Ÿ“œ SIMILAR VOLUMES

Oxidation of benzyl alcohols by nitrous
Oxidation of benzyl alcohols by nitrous and nitric acids in strong sulfuric acid media
โœ David S. Ross; Chee-Liang Gu; Georgina P. Hum; Ripudaman Malhotra ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 505 KB

We have studied the oxidation of benzyl alcohols by nitrous and nitric acid in sulfuric acid media. The oxidation by nitrous acid is rapid and has an activation energy of 10.6 -t 0.8 kcal mol-'. A Hammett plot of logkp vs. u -is linear with a p value of -1.4. The oxidation by nitric acid in sulfuric