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Oxidation of Aryl Trityl Sulfides with Hydrogen Peroxide

✍ Scribed by Gregg, D. C.; Blood, C. A.; Weiman, D. E.

Book ID
126408521
Publisher
American Chemical Society
Year
1953
Tongue
English
Weight
165 KB
Volume
75
Category
Article
ISSN
0002-7863

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TMSCl-promoted selective oxidation of su
TMSCl-promoted selective oxidation of sulfides to sulfoxides with hydrogen peroxide
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Selective oxidation of sulfides to sulfoxides is achieved using H 2 O 2 and TMSCl as the promotor. Aromatic and aliphatic sulfides are oxidized to sulfoxides in excellent yields and in short reaction times. Different functional groups including ketone, alkene, ester, and alcohol are tolerated.