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Oxidation of allyl alcohol by alkaline periodate in the presence of micro amounts of palladium(II)

โœ Scribed by Gouri A. Hiremath; Prakash L. Timmanagoudar; Sharanappa T. Nandibewoor

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
92 KB
Volume
11
Category
Article
ISSN
0894-3230

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โœฆ Synopsis

The oxidation of allyl alcohol by alkaline species of periodate, H 2 IO 6 3ร€ , was found to be catalysed by micro amounts of Pd(II) in 0.2 mol dm ร€3 alkali solution. The active species of the catalyst was found to be PdCl . A mechanism involving the interaction of the catalyst and substrate in prior equilibria leading to the formation of a pcomplex is proposed and the rate is derived.

๐Ÿ“œ SIMILAR VOLUMES

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