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Oxidation of alkenes with hydrogen peroxide, catalyzed by boron trifluoride. Synthesis of vicinal methoxyalkanols

✍ Scribed by A. O. Terent’ev; K. A. Boyarinova; G. I. Nikishin

Book ID
111459612
Publisher
Springer
Year
2008
Tongue
English
Weight
175 KB
Volume
78
Category
Article
ISSN
1070-3632

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A reaction of cycloalkanone, alkanone and alkyl aryl ketone ketals with H 2 O 2 catalyzed by boron trifluoride etherate and boron trifluoride-methanol complexes was studied. A new versatile method for the synthesis of bishydroperoxides and their derivatives, viz. 1,1%-dihydroperoxyperoxides and 1,2,