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A new method for the synthesis of bishydroperoxides based on a reaction of ketals with hydrogen peroxide catalyzed by boron trifluoride complexes

✍ Scribed by Alexander O. Terent'ev; Alexander V. Kutkin; Maxim M. Platonov; Yuri N. Ogibin; Gennady I. Nikishin

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
178 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

A reaction of cycloalkanone, alkanone and alkyl aryl ketone ketals with H 2 O 2 catalyzed by boron trifluoride etherate and boron trifluoride-methanol complexes was studied. A new versatile method for the synthesis of bishydroperoxides and their derivatives, viz. 1,1%-dihydroperoxyperoxides and 1,2,4,5-tetraoxacyclohexanes, was developed based on this reaction.

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