✦ LIBER ✦
A new method for the demetallation of tricarbonyliron diene complexes by total hydrogenation with Raney nickel. Application to a very short synthesis of (+)-[6]-gingerdiol
✍ Scribed by Michel Franck-Neumann; Philippe Geoffroy; Paul Bissinger; Sylvie Adelaide
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- French
- Weight
- 87 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
H 2 , 1 bar, EtOAc, 20°C, 16 h 93% 1 recovered 2 ( R = Ac) H 2 , 10 bars, EtOH, 20°C, 16 h 99% 2 recovered Fe(CO) 3 Fe(CO) 3