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Oxidation of adamantane catalysed by imidazolylporphyrinatoiron(III) complexes and structural studies of 5-coordinating iron(III) porphyrin

✍ Scribed by Yuji Miyazaki; Akiharu Satake; Yoshiaki Kobuke


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
707 KB
Volume
283
Category
Article
ISSN
1381-1169

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Fe 3 P 5 SiO 19 has been prepared by solid state reaction of Fe(PO 3 ) 3 , FePO 4 , and SiO 2 at 10003C. The structure has been determined from a single crystal through direct methods and di4erence Fourier synthesis and re5ned to R ‫؍‬ 0.052. The unit cell is hexagonal, space group P6 3 , with a ‫؍‬