✍ Scribed by R. Giannandrea; P. Mastrorilli; C.F. Nobile; G.P. Suranna
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The Co(H)-catalysed oxidation of alkyl-and aryI-sulfides was achieved under homogeneous and heterogeneous conditions using oxygen or air as the oxidant in the presence of excess aldehyde. The reactions in the homogeneous phase were carried out using the soiuble Co(acac), or WAAEMA), complexes IAAEMA
Aromatic a-hydroxyketones were easily oxidized by dioxygen in the presence of excess aldehyde or aldoacetal with catalytic amount of Co(II) or Fe(II1) complexes, under homogeneous and heterogeneous conditions. Co(acac), or Fe(acac), were the catalysts used in homogeneous phase reactions whereas Co(I
The epoxidation of linear and cyclic olefins was catalysed by iron( III), nickel(II) and cobalt(I1) centres immobilized on insoluble polymers. The latter were obtained by reaction of the polymerizable complexes of Fe( III), Ni( II) and Co( II) with 2-(acetoacetoxy)etbyl metbacrylate with acrylamides