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Oxidation of activated methylene groups to ketones catalyzed by new iron phosphinooxazoline complexes and by iron(II) triflate

✍ Scribed by Matthew Lenze; Eike B. Bauer


Book ID
104059198
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
584 KB
Volume
309
Category
Article
ISSN
1381-1169

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The catalync p-benzoqumone or au oxldaaon of benzoin to bennl was camed out m the presence of Pen&-o-xyl)#-(o-xyl = o-xylene-a. a'-&thlolate) or [Fen(S+Bu)&-m a ratlo [benzomlficatalyst] = 20/l m DMF at 25 'C Under such mild reacnon condmons, the Fe(II) thiolate complex exhibited high catalync activ