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Oxidation of 1,2-diphenyl-3,4-diphosphinidenecyclobutene on the group-6 metal tetracarbonyl complexes

✍ Scribed by Masaaki Yoshifuji; Yoshito Ichikawa; Kozo Toyota


Book ID
104256491
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
239 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


The group-6 metal(0) tetracarbonyl complexes of a sterically protected 3,4diphosphinidenecyclobutene were irradiated with light in the presence of oxygen to give tetracarbonyl[2,3-dibenzoyl-l,4-diphospha-l,3-butadiene]metal(0) complexes, and the structures were confirmed by X-ray analysis.


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## Abstract The new complexes (Ln(Dpbs)~2~ Β· (H~2~O)~4~) Dpbs Β· nH~2~O, where Dpbs = 4‐(3,5‐Diphenyl‐2‐pyrazolin‐1‐yl)benzenesulfonate ion, n = 0 or 2, have been synthesized and were characterized by elemental analyses, conductivity measurements, solubility, X‐ray powder patterns, thermal analysis,