Oxidation of 1,2-diphenyl-3,4-diphosphinidenecyclobutene on the group-6 metal tetracarbonyl complexes
β Scribed by Masaaki Yoshifuji; Yoshito Ichikawa; Kozo Toyota
- Book ID
- 104256491
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 239 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The group-6 metal(0) tetracarbonyl complexes of a sterically protected 3,4diphosphinidenecyclobutene were irradiated with light in the presence of oxygen to give tetracarbonyl[2,3-dibenzoyl-l,4-diphospha-l,3-butadiene]metal(0) complexes, and the structures were confirmed by X-ray analysis.
π SIMILAR VOLUMES
## Abstract The new complexes (Ln(Dpbs)~2~ Β· (H~2~O)~4~) Dpbs Β· nH~2~O, where Dpbs = 4β(3,5βDiphenylβ2βpyrazolinβ1βyl)benzenesulfonate ion, n = 0 or 2, have been synthesized and were characterized by elemental analyses, conductivity measurements, solubility, Xβray powder patterns, thermal analysis,