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Oxazolines. XIV. Asymmetric synthesis of R and S dialkylacetic acids from a single chiral oxazoline

✍ Scribed by Meyers, A. I.; Knaus, Gerald


Book ID
126124138
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
362 KB
Volume
96
Category
Article
ISSN
0002-7863

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Asymmetric synthesis using Ξ±,Ξ²-unsaturat
✍ Gen-ichi Tsuchihashi; Shuichi Mitamura; Katsuyuki Ogura πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 French βš– 245 KB

We previously reported that the Michael addltlon of dlethyl malonate to (+)-(R)-tm-B-styryl p-tolyl sulfoxide [(+)-I] In a usual condltlon (EtONa/ EtOH) resulted In the dominant formation of IIIa wrth respect to its diastereomer IIIb.