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Oxazoline N -Oxide-Mediated [2+3] Cycloadditions. Application to a Synthesis of (−)-Tetrahydrolipstatin

✍ Scribed by Dirat, O.; Kouklovsky, C.; Langlois, Yves

Book ID
120176008
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
44 KB
Volume
1
Category
Article
ISSN
1523-7060

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📜 SIMILAR VOLUMES

Oxazoline N-Oxide-Mediated [2+3] Cycload
Oxazoline N-Oxide-Mediated [2+3] Cycloadditions: New Access to Quaternary Asymmetric Centres
✍ Stéphane Collon; Cyrille Kouklovsky; Yves Langlois 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 138 KB

Cycloadditions between camphor-derived oxazoline N-oxide 1 and dipolarophiles 5 or 8 afforded adducts 6 and 9, respectively, with almost complete regio-and stereoselectivity depending on the substitution patterns of the dipolarophiles.