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Oxazolidines. 2. Synthesis of 2-methyloxazolidines by cyclization of vinyl ethers of 1, 2-amino alcohols

โœ Scribed by B. F. Kukharev; V. K. Stankevich; G. R. Klimenko; V. P. Terent'eva; V. A. Kukhareva


Book ID
112369131
Publisher
Springer US
Year
1986
Tongue
English
Weight
247 KB
Volume
22
Category
Article
ISSN
0009-3122

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Synthesis of chiral oxazolidin-2-ones by
โœ Marta Feroci; Armando Gennaro; Achille Inesi; Monica Orsini; Laura Palombi ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 316 KB

An improved electrochemical synthesis of chiral oxazolidin-2-ones from chiral 1,2-amino alcohols is obtained by direct electrolysis of solutions of MeCN-TEAP containing the amino alcohol, with subsequent CO 2 bubbling and addition of TsCl. This synthesis avoids any addition of bases or probases and