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Oscillatory behavior during the oxygen oxidation of ascorbic acid

✍ Scribed by Jack Young; Boris Franzus; Thomas T.-S. Huang

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 514 KB
Volume: 14
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550140704

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✦ Synopsis

Abstract

The oscillatory phenomenon was observed in aqueous solution during the oxidation of ascorbic acid by oxygen. Even though the exact number and amplitude of the oscillations could not be exactly duplicated for each and every run, such factors as temperature, concentration of ascorbic acid, cupric ions, and pH affecting the oscillatory behavior were studied, and those regions where oscillations occurred were delineated. A mechanism consistent with the oscillatory behavior is proposed and discussed.

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