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Orthopalladated and -platinated Bulky Triarylphosphite Complexes: Synthesis, Reactivity and Application as High-Activity Catalysts for Suzuki and Stille Coupling Reactions.

✍ Scribed by Robin B. Bedford; Samantha L. Hazelwood; Michael E. Limmert; David A. Albisson; Sylvia M. Draper; P. Noelle Scully; Simon J. Coles; Michael B. Hursthouse

Book ID: 101950085
Publisher: John Wiley and Sons
Year: 2003
Weight: 144 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200345053

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The coupling of aryl halides with aryl boronic acids, the Suzuki reaction (Scheme 1), is one of the most powerful and versatile methods for the synthesis of biaryls. There has recently been considerable interest in the development of new catalysts that can couple aryl chlorides because of the lower