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Ortho-Selective Allylation of 2-Pyridylarenes with Allyl Acetates Catalyzed by Ruthenium Complexes

โœ Scribed by Oi, Shuichi; Tanaka, Yoshikazu; Inoue, Yoshio


Book ID
126106669
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
112 KB
Volume
25
Category
Article
ISSN
0276-7333

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Ruthenium-catalyzed linear selective all
โœ Motoi Kawatsura; Fumio Ata; Takuya Hirakawa; Shuichi Hayase; Toshiyuki Itoh ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 168 KB

The ruthenium-catalyzed highly linear selective allylic amination of monosubstituted allylic acetates with secondary amines was developed. The regioselectivity was controlled by the Ru 3 (CO) 12 /2-DPPBA catalyst, and a linear-type aminated product was obtained as a single regioisomer.