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Ortho effects in organic molecules on electron impact. VI—Ortho effects of a carboxyl group in N-substituted anilines

✍ Scribed by D. V. Ramana; M. Vairamani

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
228 KB
Volume
14
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The unusual fragments noticed in the mass spectra of N‐benzyl‐ and N,N‐dibenzylanthranilic acids have been explained on the basis of the ortho interaction of the carboxyl group with the N‐benzyl‐ and N,N‐dibenzyl moieties.

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## Abstract The mass spectrum of __o__‐picolinotoluidide gives rise to three major fragments at m/z 184, m/z 169 and m/z 168, corresponding to the loss of CO from the molecular ion followed by the loss of ṄH~2~ and ĊH~3~ by independent pathways. It has been shown that the __ortho__ methyl group and