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Ortho effects in organic molecules on electron-impact I—Oxidation of olefinic double bond by the ortho nitro group in stilbazoles

✍ Scribed by D. V. Ramana; M. Vairamani

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
179 KB
Volume
9
Category
Article
ISSN
1076-5174

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Double oxygen migration to sulphur from the ortho-nitro group leading to eliminations of SO2 and 'S02H from the molecular ions and single oxygen transfer to the olefinic double bond in the sidechain giving rise to the most abundant ion at m/z 138 have been observed in 2-nitrophenyl styryl sulphides