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Origins of the enantioselectivity observed in oxazaborolidine-catalyzed reductions of ketones

✍ Scribed by Jones, Deborah K.; Liotta, Dennis C.; Shinkai, Ichiro; Mathre, David J.

Book ID
115476543
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
267 KB
Volume
58
Category
Article
ISSN
0022-3263

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Cyclic meso-imides such as the cyclic cis-3&disubstituted succinimides 1 farm an interesting and useful class of starting mater% in the field of asymmetric synthesis. A single, enantioselective transfoxmation, naw9y a reduction of one of the carbonyls, leads to a product with three contiguous stereo