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Highly enantioselective reduction of prochiral ketones with N,N-diethylaniline·borane (DEANB) in oxazaborolidine-catalyzed reductions

✍ Scribed by Ashok M. Salunkhe; Elizabeth R. Burkhardt

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
251 KB
Volume
38
Category
Article
ISSN
0040-4039

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## Abstract The effect of borane source on enantioselectivity in the enantiopure oxazaborolidine‐catalyzed asymmetric borane reduction of ketones has been investigated by using (__S__)‐3,1,2‐oxazaborobicyclo[3.3.0]octane and (__S__)‐7,3,1,2‐thiaxazaborobicyclo[3.3.0]octane as catalysts. The results