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Origin of the bridge bond in [1,1,1]propellane

✍ Scribed by Tapas Kar; Karl Jug

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 428 KB
Volume: 256
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(96)00415-0

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✦ Synopsis

The nature of bonding in [ 1,1,1 ]propellane has been discussed on the basis of localized MOs and bond indices. The present investigation does not support the presence of multi-center bonds in propellane as has been claimed earlier. The main contribution to the central bond of [1,1,1]propellane comes from the HOMO.

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