The occurrence of low-temperature triplet-triplet annihilation in 1.4-dibromonaphthalene is strongly correlated with the presence of molecules of the isomer 1,Sdibromonaphthalene. The main part of the delayed fluorescence ori@ates from thii guest molecule. The crystal structure of 1,Sdibromonaphthal
Origin of low-temperature delayed fluorescence in cyanine dyes
β Scribed by Annabel A. Muenter; Walter Cooper
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 422 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The delayed nuorcscence found in rigid-glass solutions of cyanine dyes is shown to result from the presence of lrace quantities of phosphorescent impurities
and not from n lorv-encrg photoionization process, as previously suggesred. For quinoline cyanine dyes, lhc predomiwnt impurities are idcnrified as quinoloncs, highly phosphorescent compounds formed by osidalive degradation of the dyes.
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A study of the low-temperature luminescence of neat crystalline 2,2'-biquinoline (BQ) is presented. The 2 K spectrum is comprised of intense, broad components in the 380-500 nm region, with less inte..lse, structured bands in the 500-575 nm tee.ion. Both bands exhibit different degrees of metastabil
The temperature dependence of emission spectra and their decay parameters for pyromellitic dianhydride-phenanthrene chargetransfer crystals have been investigated between 1.7 and 300 K. It has been established that the delayed fluorescence originates from triplet-triplet annihilation at temperatures