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Orientational effects on cyclopropyl participation in the thermolysis of azo compounds. Assessment of the endo configuration

✍ Scribed by Allred, Evan L.; Voorhees, Kent J.

Book ID
126979983
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
238 KB
Volume
95
Category
Article
ISSN
0002-7863

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## Abstract The ^13^C NMR spectra of singly ^15^N‐labelled __Z__/__E__ isomers of azo and diazo compounds were recorded. The ^1^__J__(^13^C^15^N) coupling constants are strongly dependent on the geometrical configuration of the azo group, the relative position of the lone pair of electrons at the n