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Influence of the Z/E configuration on the 13C15N coupling conditions 1J(13C15N) in aromatic azo and diazo compounds

✍ Scribed by S. Simova; E. Fanghänel; R. Radeglia

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
417 KB
Volume
21
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^13^C NMR spectra of singly ^15^N‐labelled Z/E isomers of azo and diazo compounds were recorded. The ^1^J(^13^C^15^N) coupling constants are strongly dependent on the geometrical configuration of the azo group, the relative position of the lone pair of electrons at the non‐coupling azo nitrogen atom having a decisive influence.

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