𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Orientational effects in the addition of acetylthiosulfenyl chloride to olefins

✍ Scribed by Mueller, Wolfgang Heinz; Butler, Peter Earle


Book ID
127194821
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
584 KB
Volume
32
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Polar Effects in the Addition of Alkyl R
✍ Priv.-Doz. Dr. Bernd Giese; Dipl.-Chem. JΓΌrgen Meister πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 English βš– 198 KB πŸ‘ 2 views

**The presence of a negative partial charge on the benzylic carbon atom in the transition state** __(1)__ can be deduced from the experimentally determinable Hammett Ο± values. Alkyl radicals R^Λ™^ are accordingly seen to develop nucleophilic properties during addition to olefins. equation image