Triplet-state ESR spectra show that when the aromatic molecules anthracene, anthracene-d,,,, terphenyl, and acridine are dissolved m stretched, low-density polyethylene films, a fraction of these solute molecules become oriented with their X axis along the stretch direction but with their XY planes
Orientation and phosphorescence polarization of planar hetero-aromatic molecules in stretched polyethylene films
โ Scribed by J.J. Dekkers; G.Ph. Hoornweg; W.P. Cofino; C. MaClean; N.H. Velthorst
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 472 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The genera! applk=bdity of the strrtchcd fdm technique has been studied from lumincscenrr polarization data of the rehtrti home-md hetero-aromrrtic compounds (~0 benzene zrnd p) rnzinr zrnd (b) ffuorene. mrbszole and drbenzofumn. It is shot" that corresponding molecules are oriented similarly in stretched poIyethyIene tiims. The phosphorescence pokri-n&n&t= uf the rumpounds quinoxzdiie. carbazole_ rnphthniene and tluorene xe comp~rrd and interpreted qu;llitatheI) on the basis ofspin-orbit and vrbronic couplin,y.
๐ SIMILAR VOLUMES
A study of the linear dichroism and fluorescence polarization of diphenylpolyenes (CeHs -(CLi=CH)]r-Cells) wirh II = 1.2, X.4.6. 8 in stretched polyethylene films sho\vs tllat the polyencs orient in the anisotropic matris with their Iransition dipole (emission and absorption, n + IT\*) aligned with