The reaction of dibutyltin oxide with Schiff bases derived from sulpha drugs in 1:1 molar ratio leads to the formation of a new series of organotin(IV) complexes. An attempt has been made to probe their structure on the basis of UV, IR, NMR ( 1 H, 13 C and 119 Sn) and Mo Β¨ssbauer spectral studies. A
Organotin(IV) complexes of biologically active Schiff bases derived from heterocyclic ketones and sulpha drugs
β Scribed by Har Lal Singh; S. Varshney; A. K. Varshney
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 53 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0268-2605
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β¦ Synopsis
Some new hexa-coordinated organotin complexes [Bu 2 Sn(NN) 2 ] (where NN is the anion of various Schiff bases) have been synthesized and characterized on the basis of elemental analysis, conductivity measurements, molecular weight determination, and ultraviolet, infrared and multinuclear magnetic resonance ( 1 H, 13 C and 119Sn) spectral studies. A few representative complexes have also been screened for their antibacterial and antifungal activity and found to be quite active in this respect.
π SIMILAR VOLUMES
Equimolar reactions of dibutyltin(IV) oxide with Schiff bases derived from amino-acids led to the formation of a new series of dibutyltin(IV) complexes of general formula, Bu 2 SnL [L = dianion of tridentate Schiff bases derived from the condensation of 2-hydroxy-1-naphthaldehyde or acetyl acetone w