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Organosilyl and organogermyl nitroxides. New radical rearrangement

✍ Scribed by West, Robert.; Boudjouk, Philip.


Book ID
126816317
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
677 KB
Volume
95
Category
Article
ISSN
0002-7863

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## Abstract The synthesis of the readily available racemate of the nitroxide radical 5 is described. The product exhibits exclusively the __trans__ configuration. The __cis__ product was not obtained. Optically pure enantiomers of 5 were isolated in gram quantities by chiral HPLC. Thus, separation