Organosilicon iminamino radicals from the addition of silyl radicals to diphenyldiazomethane
✍ Scribed by Gaspar, Peter P.; Ho, Chi-Tang; Choo, Kwang Yul
- Book ID
- 127327743
- Publisher
- American Chemical Society
- Year
- 1974
- Tongue
- English
- Weight
- 404 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The mechanism of addition reactions of radicals formed during thermal decomposition of benzoyl peroxide with various chloro-substituted p-benzoquinones has been studied by the ESR technique in various solvents. The ESR spectra of the intermediate radicals show that addition occurs at the carbonyl ox
The reaction of methyl radicals (Me) with hexafluoroacetone (HFA), generated from ditertiary butyl peroxide (dtBP), was studied over the temperature range of 402-433 K and the pressure range of 38-111 torr. The reaction resulted in the following displacement process taking place: where TFA refers t
The addition of methyl radicals to tetrafluoroethylene in the gas phase has been studied over the temperature range 8O-18O0C, using a material balance method. CH, + C,F4 -+ CH,C,F, Arrhenius parameters of 1011.95\*0.23 (mole-l cm3 sec-l) and 5.7 f 0.4 (kcal/mole) have been measured for the addition
## Abstract The addition of methyl radicals to hexafluoropropylene has been studied over the temperature range 81°–203°C using a mass‐balance technique involving the photolysis of biacetyl in the presence of hexafluoropropylene–isobutane mixtures. For the reaction the rate constant is given by th