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Addition of radicals to quinones—II. ESR spectra of radicals derived from fluoranil

✍ Scribed by T.L. Simandi; A. Rockenbauer; F. Tüdős


Book ID
107753870
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
316 KB
Volume
19
Category
Article
ISSN
0014-3057

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📜 SIMILAR VOLUMES


Addition of radicals to quinones—I. ESR
✍ T.L. Simándi; A. Rockenbauer; F. Tüdös 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 376 KB

The mechanism of addition reactions of radicals formed during thermal decomposition of benzoyl peroxide with various chloro-substituted p-benzoquinones has been studied by the ESR technique in various solvents. The ESR spectra of the intermediate radicals show that addition occurs at the carbonyl ox

Addition of radicals to quinones. ESR st
✍ Tatiana L. Simándi; Antal Rockenbauer; LászlóI. Simándi 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 316 KB

## IReactions of 3,3',5,5'-tetra-ferz-butylstilbene-4,4'-quinone with free radicals from the decomposition of azo compounds and peroxides (R') have been studied by ESR spectroscopy. Relatively stable phenoxyl+,pe free radicals are formed via addition of R' across the exo C=C bond. Their coupling c