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Organoselenium chemistry. Dealkylation of amines with benzeneselenol

โœ Scribed by Reich, Hans J.; Cohen, Martin L.


Book ID
120257977
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
553 KB
Volume
44
Category
Article
ISSN
0022-3263

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The dealkylation of tertiary aliphatic a
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Phenyl chlorothionoformate reacts rapidly with aliphatic amines at 20ยฐC to give a thiourethane and an alkyl chloride. The urethanes are readily converted to the secondary amine salt by reaction with dimethyl sulfate, followed by hydrolysis with water. Rates of reaction, and alkyl group cleavage sele