Dealkylation of aromatic tertiary amines with formates
β Scribed by Sekiya, Minoru; Tomie, Masayasu; Leonard, Nelson J.
- Book ID
- 127136473
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 760 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Phenyl chlorothionoformate reacts rapidly with aliphatic amines at 20Β°C to give a thiourethane and an alkyl chloride. The urethanes are readily converted to the secondary amine salt by reaction with dimethyl sulfate, followed by hydrolysis with water. Rates of reaction, and alkyl group cleavage sele
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