✦ LIBER ✦

Organometallics in ethylene polymerization with a catalyst system TiCl4/Al(C2H5)2Cl/Mg(C6H5)2: 2. Polymerization process in pseudo-solution

✍ Scribed by L Petkov; Ph Radenkov; R Kyrtcheva

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 315 KB
Volume: 19
Category: Article
ISSN: 0032-3861
DOI: 10.1016/0032-3861(78)90284-7

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Organometallics in ethylene polymerizati

Organometallics in ethylene polymerization with a catalyst system TiCl4/Al(C2H5)2Cl/Mg(C6H5)2: 1. Suspension polymerization process

✍ L Petkov; R Kyrtcheva; Ph Radenkov; D Dobreva 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 246 KB

Filling of polyethylene by inorganic fil

Filling of polyethylene by inorganic filler compounds during polymerization on the catalyst system TiCl4(C2H5)2AlCl(C6H5)2Mg

✍ D. Damyanov; Iv. Ivanov; M. Velikova 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 288 KB

It is shown that the system TiC14-(C2Hs)2AICI-(C6Hs)2Mg is highly efficient and very promising as a catalyst of the filling of polyethylene during the polymerization with inorganic fillers (chalk, marble powder, perlite, kaolin and dolomite). The preliminary activation of the filler, the formation t

Polymerization of propylene by the Ziegl

Polymerization of propylene by the Ziegler catalysts systems α-TiCl3Al(C2H5)3 and supported TiCl4Al(C2H5)3

✍ A. Muñoz-Escalona; J. Villalba 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 416 KB

Influence of the carrier characteristics

Influence of the carrier characteristics on the catalytic activity of supported TiCl4/Al(C2H5)2Cl Ziegler catalyst in the ethylene polymerization

✍ A. Muñoz-Escalona; A. Martín; J. Hidalgo 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 525 KB

The effect of the carrier characteristics, such as specific surface area and acidity, on the activity of supported Ziegler catalyst in the ethylene polymerization has been investigated. Silica-gel and silica-alumina, containing various quantities of alumina (5, 13 and 25 wt-'~J~,) and also modified

Kinetic laws of ethylene polymerization

Kinetic laws of ethylene polymerization in the presence of homogeneous catalysts including titanocene and Al(C2H5)2Cl in ethyl chloride medium and mathematical description of the process—I. Ethylene polymerization in the presence of the catalytic system Al(C2H5)2Cl-“Blue complex”

✍ A.V. Agasaryan; G.P. Belov; S.P. Davtyan; M.L. Eritsyan 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 408 KB

Effect of ethylene concentration, catalyst component and their molar ratio on the polymerization stationary rate, the yield and molecular weight of the polyethylene formed have been investigated. A kinetic scheme for the ethylene polymerization is proposed: a mathematical description of the process

Polymerization of propene with a rac-(CH

Polymerization of propene with a rac-(CH3)2Si(2,4-(CH3)2C5H3)(3′,5′-(CH3)2C5H3)ZrCl2/MAO/SiO2-Al(iC4H9)3 catalyst system

✍ Kazuo Soga; Manabu Kaminaka 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 758 KB