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Kinetic laws of ethylene polymerization in the presence of homogeneous catalysts including titanocene and Al(C2H5)2Cl in ethyl chloride medium and mathematical description of the process—I. Ethylene polymerization in the presence of the catalytic system Al(C2H5)2Cl-“Blue complex”

✍ Scribed by A.V. Agasaryan; G.P. Belov; S.P. Davtyan; M.L. Eritsyan

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
408 KB
Volume
17
Category
Article
ISSN
0014-3057

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✦ Synopsis

Effect of ethylene concentration, catalyst component and their molar ratio on the polymerization stationary rate, the yield and molecular weight of the polyethylene formed have been investigated. A kinetic scheme for the ethylene polymerization is proposed: a mathematical description of the process is made and the rate constants of some stages are calculated.

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