𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On the character of molecular weight distribution of polyethylene produced in the presence of the homogeneous catalytic system (C5H5)2TiCl2Al(C2H5)2Cl

✍ Scribed by A.B. Agasaryan; G.P. Belov; S.P. Davtyan; M.L. Eritsyan

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
357 KB
Volume
11
Category
Article
ISSN
0014-3057

No coin nor oath required. For personal study only.

✦ Synopsis

Experimental results obtained when studying the kinetics of ethylene polymerization in toluene, as well as data on fractionating polyethylene, are analysed and compared with the results of theoretical consideration of molecular weight distribution on the basis of the proposed kinetic scheme.

The constants of the reactions of propagation, initiation, transfer and termination of polymer chains are evaluated and compared with literature data.

INTRODL CTION

📜 SIMILAR VOLUMES

Filling of polyethylene by inorganic fil
Filling of polyethylene by inorganic filler compounds during polymerization on the catalyst system TiCl4(C2H5)2AlCl(C6H5)2Mg
✍ D. Damyanov; Iv. Ivanov; M. Velikova 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 288 KB

It is shown that the system TiC14-(C2Hs)2AICI-(C6Hs)2Mg is highly efficient and very promising as a catalyst of the filling of polyethylene during the polymerization with inorganic fillers (chalk, marble powder, perlite, kaolin and dolomite). The preliminary activation of the filler, the formation t

ChemInform Abstract: Catalytic Dechlorin
ChemInform Abstract: Catalytic Dechlorination of Aromatic Chlorides Using Grignard Reagents in the Presence of (C5H5)2TiCl2.
✍ Ryuichiro Hara; Kimihiko Sato; Wen-Hua Sun; Tamotsu Takahashi 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

## Catalytic Dechlorination of Aromatic Chlorides Using Grignard Reagents in the Presence of (C 5 H 5 ) 2 TiCl 2 . -The dechlorination of alkyl chlorides is also attempted under similar conditions. Thus, 1-chlorooctane gives octane in a moderate yield of 64% and isomers of octenes are detected as

Kinetic laws of ethylene polymerization
Kinetic laws of ethylene polymerization in the presence of homogeneous catalysts including titanocene and Al(C2H5)2Cl in ethyl chloride medium and mathematical description of the process—I. Ethylene polymerization in the presence of the catalytic system Al(C2H5)2Cl-“Blue complex”
✍ A.V. Agasaryan; G.P. Belov; S.P. Davtyan; M.L. Eritsyan 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 408 KB

Effect of ethylene concentration, catalyst component and their molar ratio on the polymerization stationary rate, the yield and molecular weight of the polyethylene formed have been investigated. A kinetic scheme for the ethylene polymerization is proposed: a mathematical description of the process

Influence of the carrier characteristics
Influence of the carrier characteristics on the catalytic activity of supported TiCl4/Al(C2H5)2Cl Ziegler catalyst in the ethylene polymerization
✍ A. Muñoz-Escalona; A. Martín; J. Hidalgo 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 525 KB

The effect of the carrier characteristics, such as specific surface area and acidity, on the activity of supported Ziegler catalyst in the ethylene polymerization has been investigated. Silica-gel and silica-alumina, containing various quantities of alumina (5, 13 and 25 wt-'~J~,) and also modified