Organometallic Syntheses || Special Solvents for Organometallic Reagents
โ Scribed by ,
- Book ID
- 120659611
- Publisher
- Elsevier
- Year
- 1981
- Weight
- 135 KB
- Category
- Article
- ISBN
- 0122349504
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๐ SIMILAR VOLUMES
The addition of vinyl, aryl and alkynyl Grignard reagents to propargyl alcohols for the direct synthesis of dihydroxydienes (7), furans (9), butenolides (10) and enediyne alcohols (11) from a one-pot reaction involving a putative magnesium chelate intermediate (3) is described. Treatment of 5-bromo-
Republic of China) [\*\*] We thank the National Sciences Council of Taiwan (NSC 89-2113-M007-022) for support of the work. Fig. 1. ORTEP drawing of complex 1 with thermal ellipsoids shown at the 50 % probability level. Selected bond distances: RuยฑC(1) = 1.900(4) , Ruยฑ C(2) = 1.896(3) , RuยฑO(3) = 2.