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Organometallic studies. XXXV. Selective hydrogenation of dienes catalyzed by arenechromium tricarbonyl complexes

✍ Scribed by M. Cais; A. Rejoan


Book ID
114041471
Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
871 KB
Volume
4
Category
Article
ISSN
0020-1693

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Organometallic studies, XXIV. Selective
✍ Michael Cais; E.N. Frankel; A. Rejoan 📂 Article 📅 1968 🏛 Elsevier Science 🌐 French ⚖ 238 KB

The current interest in homogeneous catalysis (3) prompts us to report some preliminary results on the remarkable effectiveness of arenechromium tricarbonyl complexes as catalysts in the selective hydrogenation of conjugated olefins. Methyl sorbate (methyl 2,4-hexadienoate) was chosen as substrate

Selective hydrogenation of dienes to mon
✍ Giorgio Strukul; Giovanni Carturan 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 484 KB

diene and 1,7'-octadiene to the corresponding monoenes has been carried out under mild conditions. using different (allyl)Pd(II) den'vatives in NJdimethylacetamide solution. Experiments on the I,3-COD system suggest a mechanism involving the formation of hydrido-Pd(II) species followed by insertion