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Organometallic polymers. II. Crosslinking of ferrocenylene–methylene-type polymers

✍ Scribed by Alon Gal; Michael Cais; David H. Kohn


Book ID
102735137
Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
659 KB
Volume
15
Category
Article
ISSN
0021-8995

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✦ Synopsis


Abstract

Poly(ferrocenylene‐methylmethylene) (PFMM) was prepared and subsequently crosslinked by the aid of either 1,1'‐bis(α‐hydroxyethyl)ferrocene or polyfunctional ferrocene polymers, containing reactive‐CH~2~OH or‐CH(CH~3~)OH groups. The thermal behavior of both the primary polymer and the thermoset was investigated. The solubility parameter of PFMM was determined and the degree of crosslinking was studied by solvent swelling and sol fraction measurements. Various thermosetting structural composites were prepared and subjected to mechanical testing.


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