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Organometallic Iridium(III) Cyclopentadienyl Anticancer Complexes Containing C,N-Chelating Ligands

✍ Scribed by Liu, Zhe; Habtemariam, Abraha; Pizarro, Ana M.; Clarkson, Guy J.; Sadler, Peter J.


Book ID
120057951
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
932 KB
Volume
30
Category
Article
ISSN
0276-7333

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## Abstract Heating [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(CH~2~CMe~2~Ph)] (1; dtbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridyl) in __p__‐xylene at 110 °C resulted in the formation of the 2‐__tert__‐butylphenyl complex [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(C~6~H~4~__t__Bu‐2)] (3). Treat