C–H Activation with Iridium(III) and Rho
C–H Activation with Iridium(III) and Rhodium(III) Alkyl Complexes Containing a 2,2′-Bipyridyl Ligand
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Xiao-Yi Yi; Ka-Wang Chan; Enrique Kwang Huang; Yiu-Keung Sau; Ian D. Williams; W
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Article
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2010
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John Wiley and Sons
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English
⚖ 427 KB
## Abstract Heating [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(CH~2~CMe~2~Ph)] (1; dtbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridyl) in __p__‐xylene at 110 °C resulted in the formation of the 2‐__tert__‐butylphenyl complex [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(C~6~H~4~__t__Bu‐2)] (3). Treat