Organometallic crystals engineering: Part 7. Construction of mixed-metal crystalline systems via electrostatic interactions and cooperative strong and weak hydrogen bonds

Crystal Engineering of Organometallic Co

Crystal Engineering of Organometallic Compounds through Cooperative Strong and Weak Hydrogen Bonds: A Simple Route to Mixed-Metal Systems

✍ Dario Braga; Lucia Maini; Fabrizia Grepioni 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB

Cooperative strong negatively charged and neutral O-H⋅⋅⋅O as well as weak charge-assisted C-H ⋅⋅⋅O hydrogen-bonding interactions have been utilized for the crystal engineering of organometallic Fe /Co and Fe /Cr sandwich complexes. A section of the structure of [(η -C H ) Cr] {[(η -C H COOH)(η -C H