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Organometallic complexes with chiral cyclometallated ligands. The synthesis of cycloplatinated complexes containing the (S) or (R)-2-NMe2C6H4CH(SiR3) (R = Me, Ph) monoanion. X-Ray crystal and molecular structure of [PtCl[CH(SiMe3)C6H4-2-NMe2](Et2S)]

✍ Scribed by Erik Wehman; Gerard van Koten; Gerard Hardeman; Casper H. Stam; Michel Pfeffer


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
549 KB
Volume
107
Category
Article
ISSN
0165-0513

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✍ Su Jing; Christopher P. Morley; Christopher A. Webster; Massimo Di Vaira πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 608 KB

## Abstract A series of linear tridentate ligands, FcE(CH~2~)~3~Eβ€²(CH~2~)~3~EFc (E, Eβ€² = Se or Te), was synthesised. Their chloropalladium(II) and chloroplatinum(II) complexes were also prepared. The new compounds were characterised by a range of spectroscopic and analytical techniques, including m