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Organometallic complexes with biological molecules. I. Diorganotin(IV)chloro protoporphyrin IX complexes: Solid-state and solution-phase characterization

✍ Scribed by Lorenzo Pellerito; Alessandro Pellerito; Francesco Maggio; Mariano Beltramini; Benedetto Salvato; Fernanda Ricchelli

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
457 KB
Volume
7
Category
Article
ISSN
0268-2605

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The synthesis, the structural features and the in vivo biological activity of diorganotin(IV) and triorganotin(IV) derivatives of [mesotetra(4-carboxyphenyl)porphine] (H 4 TPPC) are reported. Derivatives with general formula (R 2 Sn) 2 TPPC and (R 3 Sn) 4 TPPC (R = Me, Bu, and Ph) were obtained, and

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Several new triorganotin(IV) derivatives of Lhomocysteic acid (L-HCAH) with formula R 3 Sn(L-HCA) (R = Me, n Bu, Ph) have been synthesized. Their solid-state configurations were determined by IR and Mössbauer spectroscopy. The tin(IV) atom is five-coordinated in all the complexes, with the L-homocys