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Organoiodine complexes: Structural and functional variety

✍ Scribed by M. S. Chernov’yants; I. V. Burykin

Publisher
Springer
Year
2009
Tongue
English
Weight
636 KB
Volume
58
Category
Article
ISSN
1573-9171

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✍ Max Herberhold; Melanie Keller; Walter Kremnitz; Thomas Daniel; Wolfgang Milius; 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 132 KB 👁 2 views

Diphenyl diselenide reacts with [CpRh(CO) 2 ] (1) to give the dimer [CpRh(SePh)(l-SePh)] 2 (2), the solid state structure of which has been determined by X-ray analysis; the dimeric structure is retained in solution. In contrast, [Cp\*Rh(CO) 2 ] (4) gives the ionic product [Cp\*Rh(l-SePh) 3 RhCp\*][