Organocatalyzed Solvent-Free Aza-Henry Reaction: A Breakthrough in the One-Pot Synthesis of 1,2-Diamines.
β Scribed by Luca Bernardi; Bianca F. Bonini; Elena Capito; Gabriella Dessole; Mauro Comes-Franchini; Mariafancesca Fochi; Alfredo Ricci
- Book ID
- 101971484
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 37 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Zwitterionic imidazolium sulfonates are excellent catalysts for stereoselective aza-Henry reaction under solvent-free conditions. The major syn-b-nitroamine is obtained in high yields. This three-component condensation reaction catalyzed by zwitterionic-type molten salt deserves attention in its own
Acyclic Β’z-nitro ketones are easily obtained in one pot, through a solvent-free procedure by nitronldol (Henry) reaction on neutral alumina, then in situ oxidation of the nitroalkanol using wet alumina supported chromium(Vl) oxide.