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Organocatalytic synthesis of (poly)hydroxyurethanes from cyclic carbonates and amines

✍ Scribed by Lambeth, Robert H.; Henderson, Terry J.

Book ID
123580226
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
790 KB
Volume
54
Category
Article
ISSN
0032-3861

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Optically active poly(hydroxyurethane)s
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✍ Nobuhiro Kihara; Yuuji Kushida; Takeshi Endo πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 482 KB

The polyaddition of L-lysine hydrochloride and bifunctional five-membered cyclic carbonate 1 was carried out in DMAc in the presence of 1 equiv of DBU or 2 equiv of sodium hydride for 24 h to afford optically active polyurethane 2 bearing hydroxy and carboxyl group. The polyaddition of L-lysinol and