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Organocatalytic Enantioselective Nucleophilic Vinylic Substitution.

✍ Scribed by Thomas B. Poulsen; Luca Bernardi; Mark Bell; Karl Anker Joergensen


Publisher
John Wiley and Sons
Year
2007
Weight
49 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Carbonylmetallates and carbanions in aro
✍ I. P. Beletskaya; G. A. Artamkina; A. Yu. Mil'chenko; P. K. Sazonov; M. M. Shter πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 701 KB

The kinetic data on the reactions of carbonylmetallates M'M(CO).L,, with polyfluorinated arenes and alkenes are reported. The behaviour of these transition metal anionic nucleophiles is compared with the reactivity of both carbanions, and non-transition metal centred anions.