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Organocatalytic Enantioselective Nucleophilic Vinylic Substitution

✍ Scribed by Thomas B. Poulsen; Luca Bernardi; Mark Bell; Karl Anker Jørgensen


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
150 KB
Volume
45
Category
Article
ISSN
0044-8249

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Organocatalytic Enantioselective Nucleop
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Carbonylmetallates and carbanions in aro
✍ I. P. Beletskaya; G. A. Artamkina; A. Yu. Mil'chenko; P. K. Sazonov; M. M. Shter 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 701 KB

The kinetic data on the reactions of carbonylmetallates M'M(CO).L,, with polyfluorinated arenes and alkenes are reported. The behaviour of these transition metal anionic nucleophiles is compared with the reactivity of both carbanions, and non-transition metal centred anions.